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1.
Adv Mater ; 35(41): e2302979, 2023 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-37378645

RESUMO

The application of high-entropy oxide (HEO) has attracted significant attention in recent years owing to their unique structural characteristics, such as excellent electrochemical properties and long-term cycling stability. However, the application of resistive random-access memory (RRAM) has not been extensively studied, and the switching mechanism of HEO-based RRAM has yet to be thoroughly investigated. In this study, HEO (Cr, Mn, Fe, Co, Ni)3 O4 with a spinel structure is epitaxially grown on a Nb:STO conductive substrate, and Pt metal is deposited as the top electrode. After the resistive-switching operation, some regions of the spinel structure are transformed into a rock-salt structure and analyzed using advanced transmission electron microscopy and scanning transmission electron microscopy. From the results of X-ray photoelectron spectroscopy and electron energy loss spectroscopy, only specific elements would change their valence state, which results in excellent resistive-switching properties with a high on/off ratio on the order of 105 , outstanding endurance (>4550 cycles), long retention time (>104 s), and high stability, which suggests that HEO is a promising RRAM material.

2.
STAR Protoc ; 3(1): 101066, 2022 03 18.
Artigo em Inglês | MEDLINE | ID: mdl-35024625

RESUMO

The protocol outlines the steps for growing silica nanowires on various substrates such as glass and stainless-steel foil. Silica nanowires are grown by thermal chemical vapor deposition via a vapor-liquid-solid mechanism, in which silicon wafers are used as silicon sources and platinum films as catalysts. This protocol can be used to grow silica nanowires on other substrates such as quartz filter, quartz sphere, alumina plate, and silicon wafer, provided the substrate materials can tolerate the temperature during process heating. For complete details on the use and execution of this profile, please refer to Lee et al. (2019), Tsai and Shieh (2019), and Tsai et al. (2021).


Assuntos
Nanofios , Óxido de Alumínio , Gases , Nanofios/química , Quartzo , Silício/química , Dióxido de Silício/química
3.
iScience ; 24(7): 102746, 2021 Jul 23.
Artigo em Inglês | MEDLINE | ID: mdl-34308286

RESUMO

Water in motion is a significant energy source worldwide, but the surface energy of water is rarely utilized as a power source. In this study, we made metals unsinkable and able to jump out of the water by harvesting the water surface energy. This effect is attributed to the enhanced floating ability of the nanostructures on copper and stainless steel foil surfaces. Sufficiently thin hydrophobic metals can slowly float underwater through air trapping at the surface and then rapidly leap out of the water on contact with the water-air interface. The mechanism is related to the surface energy of the water, which contributes to the 15 mg metals with a power of 0.49 µW experiencing rapid changes in velocity and acceleration at the interface. The conversion of surface energy to eject nanostructured hydrophobic materials from the liquid surface may lead to new solid-liquid separation techniques.

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